Complexes of molybdenum(VI) oxide tetrafluoride and molybdenum(VI) dioxide difluoride with neutral N- and O-donor ligands
نویسندگان
چکیده
منابع مشابه
Synthesis and structural characterisation of germanium(II) halide complexes with neutral N-donor ligands.
The Ge(II) complexes [GeX(2)(L-L)] (L-L = 1,10-phen (X = Cl, Br); L-L = Me(2)N(CH(2))(2)NMe(2), 2,2'-bipy (X = Cl)), [GeX(L-L)][GeX(3)] (L-L = 2,2'-bipy (X = Br); L-L = pmdta (MeN(CH(2)CH(2)NMe(2))(2)) (X = Cl, Br)) have been prepared and their crystal structures determined. The crystal structure of [GeCl(2){Me(2)N(CH(2))(2)NMe(2)}] shows a weakly associated centrosymmetric dimer based upon dis...
متن کاملCoordination complexes of NbX5 (X = F, Cl) with (N,O)- and (O,O)-donor ligands and the first X-ray characterization of a neutral NbF5 adduct.
A variety of fairly air-stable complexes were prepared by straightforward reactions of NbX5 (X = F, Cl) with a series of potential bidentate (N,O)- and (O,O)-donor ligands in CH2Cl2. NbF5 reacted with equimolar amounts of 2-[(2,6-diisopropylphenyl)iminomethyl]phenol (dpimpH) and 2-benzoyl-6-hydroxy-6-phenylpentafulvene (bhpfH) to afford the mononuclear complexes NbF5[κ(1)(O)-OC6H4CH=NHC6H3(CHMe...
متن کاملMetal Saccharinates and Their Complexes with N-donor Ligands*
The structural data for metal saccharinates and metal complexes including saccharin and various coordinated mono(imidazole, pyridine) or polycyclic N-donor ligands (2,2'-bipyridine, 1,10-phenantroline) were retrieved from the Cambridge Structural Database and analyzed. The influence of the nature of the metal ion and of the type of the metal-to-ligand bonding on the saccharinato geometry was ex...
متن کاملHydrothermal synthesis of Group 13 metal trifluoride complexes with neutral N-donor ligands.
The reactions of the hydrated Group 13 fluorides, MF3·3H2O (M = Al, Ga or In) with 2,2':6',2''-terpyridyl, 2,2'-bipyridyl or 1,10-phenanthroline under hydrothermal conditions (180 °C/15 h) produced high yields of the complexes [MF3(terpy)]·3H2O, [MF3(bipy)(OH2)]·2H2O and [MF3(phen)(OH2)]. X-Ray crystal structures of [M'F3(terpy)]·3H2O (M' = Al or Ga), [M'F3(bipy)(OH2)]·2H2O and [GaF3(phen)(OH2)...
متن کاملsynthesis and dna interaction studies of new cobalt (ii) complexes containing different dinitrogen aaromatic ligands with calf thymus dna using different spectroscopy methods
در این مطالعه بر هم کنش این چهار کمپلکس با dna تیموس گوساله توسط روش های اسپکتروفتومتری، فلوریمتری، دو رنگ نمائی دورانی، و ویسکوزیمتری بررسی شدند تا اثر استخلاف های متیل بر روی لیگاندهای فنانترولین بررسی گردد.
ذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Fluorine Chemistry
سال: 2017
ISSN: 0022-1139
DOI: 10.1016/j.jfluchem.2017.06.015